Clemenpine Fragrance Oil Safety Data Sheet
STOCK FRAGRANCE
Safety Data Sheet
Safety Data Sheet – CLEMENPINE Fragrance Oil
1 PRODUCT AND COMPANY IDENTIFICATION
1.1 Product Identifier
| Product |
|---|
| CLEMENPINE E23044941 |
1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against
Perfume composition, flavor, aromatic ingredient, or blends of food additives and ingredients, for industrial use, which may be used in end-user products.
1.3 Details of the Supplier of the Safety Data Sheet
| Field | Details |
|---|---|
| Supplier | STOCK FRAGRANCE |
| Address | PO BOX 253, RIVER EDGE, NJ 07661 |
| Telephone | 347-989-4511 (Only during office hours) |
| hello@stockfragrance.com |
1.4 Emergency Telephone Number
Emergency telephone: CHEMTREC 1-703-527-3887 / 1-800-424-9300
2 HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
| Hazard Category | Classification |
|---|---|
| Physical hazards | Flam. Liq. 4: Combustible liquid. |
| Health — Skin | Skin irrit. 2: Causes skin irritation. |
| Health — Sens. | Skin Sens. 1: May cause an allergic skin reaction. |
| Health — Repro. | Repr. 2: Suspected of damaging fertility or the unborn child. |
| Environmental | Aquatic Acute 1: Very toxic to aquatic life. |
| Environmental | Aquatic Chronic 2: Toxic to aquatic life with long lasting effects. |
2.2 Label Elements
Signal Word: WARNING
Pictogram:
GHS07
GHS08
GHS09
Hazard Statements
| Code | Statement |
|---|---|
| H227 | Combustible liquid. |
| H315 | Causes skin irritation. |
| H317 | May cause an allergic skin reaction. |
| H361 | Suspected of damaging fertility or the unborn child. |
| H400 | Very toxic to aquatic life. |
| H411 | Toxic to aquatic life with long lasting effects. |
Precautionary Statements
| Code | Statement |
|---|---|
| P210 | Keep away from heat/sparks/open flames/hot surfaces. No smoking. |
| P281 | Use personal protective equipment as required. |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
| P201 | Obtain special instructions before use. |
| P261 | Avoid breathing dust/fume/gas/mist/vapors/spray. |
| P273 | Avoid release to the environment. |
| P308+P313 | IF exposed or concerned: Get medical advice/attention. |
| P333+P313 | If skin irritation or rash occurs: Get medical advice. |
| P370+P378 | In case of fire: Use water for extinction. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P391 | Collect spillage. |
| P321 | Specific treatment (see this label). |
| P362 | Take off contaminated clothing and wash before reuse. |
| P403+P235 | Store in a well-ventilated place. Keep cool. |
| P405 | Store locked up. |
| P501 | Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
| P272 | Contaminated work clothing should not be allowed out of the workplace. |
2.3 Other Hazards
None
3 COMPOSITION / INFORMATION ON INGREDIENTS
3.1 Substances
CAS-No.: Not applicable
3.2 Mixtures — Hazardous Substances
| Component | CAS | Concentration Limit | Classification |
|---|---|---|---|
| BENZYL BENZOATE | 120-51-4 | ≥ 10 % – 20 % | Acute Tox. 4 Oral, H302 / Aquatic Acute 1, H400 / Aquatic Chronic 2, H411 |
| OCTAHYDRO TETRAMETHYL ACETONAPHTONE | 54464-57-2 | ≥ 10 % – 20 % | Skin irrit. 2, H315 / Skin Sens. 1B, H317 / Aquatic Chronic 1, H410 |
| 2-tert-BUTYLCYCLOHEXYL ACETATE | 88-41-5 | ≥ 1 % – 5 % | Flam. Liq. 4, H227 / Aquatic Chronic 2, H411 |
| 2,6-dimethyloct-7-en-2-ol | 18479-58-8 | ≥ 1 % – 5 % | Flam. Liq. 4, H227 / Skin irrit. 2, H315 / Eye Irrit. 2A, H319 / STOT SE 3, H336 |
| D-LIMONENE | 5989-27-5 | ≥ 1 % – 5 % | Flam. Liq. 3, H226 / Asp. Tox. 1, H304 / Skin irrit. 2, H315 / Skin Sens. 1B, H317 / Aquatic Acute 1, H400 / Aquatic Chronic 3, H412 |
| HEXYL CINNAMAL | 101-86-0 | ≥ 1 % – 5 % | Skin Sens. 1B, H317 / Aquatic Acute 1, H400 / Aquatic Chronic 2, H411 |
| CITRAL | 5392-40-5 | ≥ 1 % – 5 % | Skin irrit. 2, H315 / Skin Sens. 1B, H317 / Eye Irrit. 2A, H319 |
| ALLYL HEXANOATE | 123-68-2 | ≥ 1 % – 5 % | Flam. Liq. 4, H227 / Acute Tox. 3 Oral, H301 / Acute Tox. 3 Dermal, H311 / Aquatic Acute 1, H400 / Aquatic Chronic 2, H411 |
| PARACYMENE | 99-87-6 | ≥ 1 % – 5 % | Flam. Liq. 3, H226 / Asp. Tox. 1, H304 / Acute Tox. 3 Inhalation, H331 / Repr. 2, H361 / Aquatic Chronic 2, H411 |
| METHYL N-METHYL ANTHRANILATE | 85-91-6 | ≥ 1 % – 5 % | Eye Irrit. 2A, H319 |
| COUMARIN | 91-64-5 | ≥ 1 % – 5 % | Acute Tox. 4 Oral, H302 / Skin Sens. 1B, H317 |
| LORENOX | 900779-74-0 | ≥ 0.1 % – 1 % | Skin Sens. 1B, H317 / Eye Irrit. 2A, H319 / Aquatic Acute 1, H400 / Aquatic Chronic 1, H410 |
| CAMPHENE | 79-92-5 | ≥ 0.1 % – 1 % | Flam. Sol. 2, H228 / Eye Irrit. 2B, H320 / Aquatic Acute 1, H400 / Aquatic Chronic 1, H410 |
| Alpha PINENE | 80-56-8 | ≥ 0.1 % – 1 % | Flam. Liq. 3, H226 / Acute Tox. 4 Oral, H302 / Asp. Tox. 1, H304 / Skin irrit. 2, H315 / Skin Sens. 1B, H317 / Aquatic Acute 1, H400 / Aquatic Chronic 1, H410 |
| DELTA 3 CARENE | 13466-78-9 | ≥ 0.1 % – 1 % | Flam. Liq. 3, H226 / Asp. Tox. 1, H304 / Skin irrit. 2, H315 / Skin Sens. 1, H317 / Acute Tox. 4 Inhalation, H332 / Aquatic Chronic 2, H411 |
| 2 DODECENAL | 4826-62-4 | ≥ 0.1 % – 1 % | Skin irrit. 2, H315 / Skin Sens. 1B, H317 / Eye Irrit. 2A, H319 / Aquatic Acute 1, H400 |
| MYRCENE | 123-35-3 | ≥ 0.1 % – 1 % | Flam. Liq. 3, H226 / Asp. Tox. 1, H304 / Skin irrit. 2, H315 / Eye Irrit. 2A, H319 / Aquatic Acute 1, H400 / Aquatic Chronic 2, H411 |
Ingredients having an occupational exposure limit value: See section 8.
4 FIRST AID MEASURES
4.1 Description of First Aid Measures
| Situation | Action |
|---|---|
| IF ON SKIN (or hair) | Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. |
| IF IN EYES | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| IF SWALLOWED | Rinse mouth. Do NOT induce vomiting. |
| IF INHALED | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Get medical attention if symptoms persist.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Never give liquid to an unconscious person.
5 FIRE-FIGHTING MEASURES
5.1 Suitable Extinguishing Media
Water, CO₂ or Foam. Avoid water in straight hose stream; will scatter and spread fire.
5.2 Special Hazards Arising from the Substance or Mixture
Avoid breathing dust or vapor. Cool containers exposed to flames with water until well after the fire is out.
5.3 Advice for Firefighters
No specific precautions.
6 ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions, Protective Equipment and Emergency Procedures
Contain spillages with sand, earth or any suitable adsorbent material.
6.2 Environmental Precautions
There must be no release into the environment.
6.3 Methods and Materials for Containment and Cleanup
Collect with non-combustible absorbent material. Flush with water. Dike for large spills.
6.4 Reference to Other Sections
See Section 8 for Personal Protective Equipment. For waste disposal, see Section 13.
7 HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Keep strict control of dust accumulation to a minimum. Maintain adequate local and general ventilation where product is handled. Avoid any sources of ignition. Good personal washing routines should be followed.
7.2 Condition for Safe Storage, Including Any Incompatibilities
Keep only in the original container in an appropriate place.
7.3 Specific End Use(s)
No specific precautions.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control Parameters
| Component | CAS | Concentration Limit | OEL (ppm) |
|---|---|---|---|
| D-LIMONENE | 5989-27-5 | ≥ 1 % – 5 % | 30 (AIHA) |
| CITRAL | 5392-40-5 | ≥ 1 % – 5 % | 5 (ACGIH) |
8.2 Exposure Controls
Discharge, treatment, or disposal may be subject to national, state, or local laws.
8.2.2 Personal Protective Equipment (PPE)
| Type | Requirement |
|---|---|
| Respiratory protection | In case of inadequate ventilation use suitable respirator. |
| Eye protection | Wear goggles/face shield. |
| Hand protection | Gloves. |
| Skin protection | Wear suitable protective clothing. Provide adequate ventilation if fumes or vapors are generated. |
9 PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical and Chemical Properties
| Property | Value |
|---|---|
| Physical State | Liquid |
| Color | Colorless to Yellow |
| Odor | Characteristic |
| pH | No data available |
| Melting Point (°C) | No data available |
| Boiling Point (°C) | No data available |
| Flash Point | 184.5 °F (84.7 °C) |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive Limits | No data available |
| Vapor Pressure | 0.09 mmHg |
| Vapor Density | No data available |
| Specific Gravity | 0.9562 / 0.9662 |
| Solubility | No data available |
| Log Pow (n-Octanol/Water) | No data available |
| Auto Ignition Temp. (°C) | No data available |
| Decomposition Temp. (°C) | No data available |
| Viscosity at 40°C | No data available |
| Explosive Properties | No data available |
| Oxidizing Properties | No data available |
| Vapor Pressure at 20°C | No data available |
| Vapor Pressure at 50°C | No data available |
9.2 Other Information
No other information noted.
10 STABILITY AND REACTIVITY
10.1 Reactivity
No data available.
10.2 Chemical Stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
No data available.
10.4 Conditions to Avoid
Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.
10.5 Incompatible Materials
No data available.
10.6 Hazardous Decomposition Products
No data available.
11 TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects
| Parameter | Value |
|---|---|
| LD50 Dermal (mg/kg) | > 5000 (Calculated) |
| LD50 Oral (mg/kg) | 2599.8 (Calculated) |
| LC50 Inhalation vapor (mg/l) | > 100 (Calculated) |
11.2 Other Toxicological Data
This product has not been subject to toxicological testing as an entity. According to available data on the constituents, the health classification criteria are met.
11.3 Information About Carcinogens
| Agency | Status |
|---|---|
| NTP | None |
| IARC | None |
| OSHA | None |
12 ECOLOGICAL INFORMATION
12.1 Toxicity
| Parameter | Value |
|---|---|
| Toxicity Fish | No data available |
| Toxicity Alga | No data available |
| Toxicity Water Flea | No data available |
| Toxicity Rat | No data available |
12.2 Persistence and Degradability
| Parameter | Value |
|---|---|
| Biodegradability | No data available |
| Hydrosolubility | No data available |
12.3 Other Eco-Toxicological Information
This product has not been subject to eco-toxicological testing as an entity. According to available data on the constituents, the environment classification criteria are met.
| Parameter | Value |
|---|---|
| Log Pow (n-Octanol/Water) | No data available |
| Bio Concentration Factor | No data available |
| Bioaccumulative Potential | No data available |
| Mobility in Soil | No data available |
| Other Adverse Effects | No data available |
13 DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Do not release into the environment. Confirm disposal procedures with environmental engineer and local regulations.
13.2 Other Information
Always keep original label’s on empty recipients (drums/pails).
14 TRANSPORT INFORMATION
14.1 DOT (Road / Rail)
| Field | Details |
|---|---|
| UN Number | 3082 |
| Proper Shipping Name | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS) |
| Hazard Class | Class 9: Miscellaneous Dangerous Substances and Articles |
| Packing Group | III |
| Environmental Hazard | Yes |
| Marine Pollutant | — |
14.2 IATA (Air)
| Field | Details |
|---|---|
| UN Number | 3082 |
| Proper Shipping Name | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS) |
| Hazard Class | Class 9: Miscellaneous Dangerous Substances and Articles |
| Packing Group | III |
| Environmental Hazard | Yes |
| Marine Pollutant | — |
14.3 IMDG (Sea)
| Field | Details |
|---|---|
| UN Number | 3082 |
| Proper Shipping Name | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS) |
| Hazard Class | Class 9: Miscellaneous Dangerous Substances and Articles |
| Packing Group | III |
| Environmental Hazard | Yes |
| Marine Pollutant | P - pollutant |
15 REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture: No recommendation given.
16 OTHER INFORMATION
16.1 Entire Text of H and P Phrases Mentioned in Chapters 2 and 3
| Code | Statement |
|---|---|
| H227 | Combustible liquid. |
| H315 | Causes skin irritation. |
| H317 | May cause an allergic skin reaction. |
| H361 | Suspected of damaging fertility or the unborn child. |
| H400 | Very toxic to aquatic life. |
| H411 | Toxic to aquatic life with long lasting effects. |
| P210 | Keep away from heat/sparks/open flames/hot surfaces. No smoking. |
| P281 | Use personal protective equipment as required. |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
| P201 | Obtain special instructions before use. |
| P261 | Avoid breathing dust/fume/gas/mist/vapors/spray. |
| P273 | Avoid release to the environment. |
| P308+P313 | IF exposed or concerned: Get medical advice/attention. |
| P333+P313 | If skin irritation or rash occurs: Get medical advice. |
| P370+P378 | In case of fire: Use water for extinction. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P391 | Collect spillage. |
| P321 | Specific treatment (see this label). |
| P362 | Take off contaminated clothing and wash before reuse. |
| P403+P235 | Store in a well-ventilated place. Keep cool. |
| P405 | Store locked up. |
| P501 | Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
| P272 | Contaminated work clothing should not be allowed out of the workplace. |
16.2 Abbreviations and Acronyms
| Abbreviation | Definition |
|---|---|
| CAS | Chemical Abstracts Service |
| CO₂ | Carbon dioxide |
| LD50 | Lethal dose 50 |
| NTP | National Toxicology Program |
| IARC | International Agency for Research on Cancer |
| OSHA | Occupational Safety and Health Administration |
| UN | United Nations |
| IMDG | International Maritime Dangerous Goods |
| IATA | International Air Transport Association |
16.3 Key Literature References and Sources for Data
This Safety Data Sheet has been prepared in accordance with the Hazard Communication Standard (HCS) and its amendments, promulgated by the US Occupational Safety and Health Administration (OSHA) – 29 CFR 1910.1200. We cannot be held responsible in the event of improper usage of this product. It is up to the user to analyse the information given and to determine appropriate handling conditions for the safe use of this product. This automatically generated safety data sheet is valid without signature.
The information provided is correct to the best of our knowledge, information and belief at the date of its publication. The information is provided as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification.
Learn more: Solvents in Fragrance Oils · How to Store Fragrance Oils
Frequently Asked Questions
What is a Safety Data Sheet (SDS) for fragrance oil?
A Safety Data Sheet (SDS) is a standardized document providing detailed hazard, safe handling, storage, and disposal information for a chemical product. For fragrance oils, the SDS follows the GHS (Globally Harmonized System) format required for commercial and professional use under OSHA's Hazard Communication Standard.
Is Clemenpine fragrance oil safe to use in candles and body care products?
Yes, when used at IFRA-compliant levels. Clemenpine has been assessed for safety in accordance with IFRA guidelines. Review the IFRA 51 Regulatory Data Sheet for maximum usage levels by product type, and this SDS for safe handling practices during production.
Does Clemenpine fragrance oil require special handling or PPE?
We recommend protective gloves and eye protection when handling fragrance oils in commercial quantities. Avoid prolonged skin contact and wash hands thoroughly after use. See Section 8 of this SDS for full personal protective equipment recommendations.
What should I do if Clemenpine fragrance oil contacts skin or eyes?
For skin contact, wash thoroughly with soap and water. For eye contact, rinse continuously with water for at least 15 minutes. If irritation persists, seek medical attention. Emergency contact: CHEMTREC 1-800-424-9300. Full first aid guidance is in Section 4 of this SDS.